4-Phenyl­sulfon­yl-2-(p-tolyl­sulfon­yl)-1H,8H-pyrrolo­[2,3-b]indole

نویسندگان

  • Jeanese C. Badenock
  • Jason A. Jordan
  • Erin T. Pelkey
  • Gordon W. Gribble
  • Jerry P. Jasinski
چکیده

The title compound, C(23)H(18)N(2)O(4)S(2), contains a pyrrolo group fused onto the plane of an indole ring with phenyl-sulfonyl and p-toluene-sulfonyl groups bonded to the indole and pyrrolo rings. The angles between the mean planes of the pyrrolo-indole ring and the phenyl-sulfonyl and p-toluene-sulfonyl rings are 73.7 (6) and 80.6 (0)°, respectively. The dihedral angle between the mean planes of the two benzene rings is 78.7 (4)°. In the crystal, both classical N-H⋯O and non-classical C-H⋯O inter-molecular hydrogen-bonding inter-actions are observed, as well as weak π-π inter-actions [centroid-centroid distances = 3.6258 (8) and 3.9298 (8) Å], which contribute to the stability of the packing.

برای دانلود رایگان متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

5-Bromo-1H-pyrrolo­[2,3-b]pyridine

In the title compound, C7H5BrN2, fused six-membered pyridine and five-membered pyrrole rings form the essentially planar aza-indole skeleton (r.m.s. deviation = 0.017 Å). In the crystal, pairs of N-H⋯N hydrogen bonds connect the mol-ecules into inversion dimers.

متن کامل

2-(1H-Pyrrolo­[2,3-b]pyridin-2-yl)pyridine

The asymmetric unit of the title compound, C12H9N3, contains two independent mol-ecules in which the dihedral angle between the pyridine and aza-indole rings are 8.23 (6) and 9.89 (2)°. In the crystal, both types of mol-ecule are connected by pairs of N-H-N hydrogen bonds into inversion dimers.

متن کامل

4-Bromo­meth­yl-1-phenyl­sulfon­yl-1H-indole

In the title mol-ecule, C(15)H(12)BrNO(2)S, the indole mean plane and phenyl ring are nearly orthogonal to each other, forming a dihedral angle of 88.19 (13)°. The Br atom is disordered over two close positions with occupancies of 0.56 (4) and 0.44 (4). The crystal packing exhibits weak inter-molecular C-H⋯π inter-actions.

متن کامل

2,3-Dihydro-1H-pyrrolo­[1,2-a]indole-9-carbonitrile

The asymmetric unit of the title compound, C12H10N2, which may serve as a model for mitosenes, contains two independent mol-ecules. The conformation of the five-membered rings in both molecules is envelope, with the central CH2-CH2-CH2 C atom at the flap in each case. In the crystal, they inter-act by a combination of weak C-H⋯N and π-π inter-actions [centroid-centroid distances = 3.616 (1) and...

متن کامل

2-(Bicyclo­[2.2.1]hept-5-en-2-yl)-1H-pyrrolo­[2,3-b]pyridine

The crystal structure of the title compound, C(14)H(14)N(2), displays inter-molecular N-H⋯N hydrogen bonds, forming dimers of enanti-omeric mol-ecules via a crystallographic centre of inversion.

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

عنوان ژورنال:

دوره 66  شماره 

صفحات  -

تاریخ انتشار 2010